DABCO-mediated [4 + 4]-domino annulation reactions of ynones and α-cyano-α,β-unsaturated ketones: Mechanisms and the role of DABCO
Sign Up to like & getrecommendations! Published in 2021 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2021.113396
Abstract: Abstract As natural products with important biological activities, eight-membered cyclic ethers can be achieved in good yields by the [4 + 4] domino annulation reactions of ynones and α-cyano-α,β-unsaturated ketones mediated by DABCO under mild conditions. To… read more here.
Keywords: annulation reactions; ynones cyano; dabco; domino annulation ... See more keywords
Synthesis, structure-activity relationship and biological evaluation of tetracationic gemini Dabco-surfactants for transdermal liposomal formulations.
Sign Up to like & getrecommendations! Published in 2019 at "International journal of pharmaceutics"
DOI: 10.1016/j.ijpharm.2019.118953
Abstract: In this study, we report the relationship between structure, self-assembly behavior and antimicrobial activity of multicationic gemini surfactants and their successful use as stabilizers of a new liposomal formulation for transdermal drug delivery. New surfactants… read more here.
Keywords: dabco surfactants; dabco dabco; dabco; liposomal formulations ... See more keywords
New dicationic DABCO-based ionic liquids: a scalable metal-free one-pot synthesis of bis-2-amino-5-arylidenethiazol-4-ones
Sign Up to like & getrecommendations! Published in 2019 at "Royal Society Open Science"
DOI: 10.1098/rsos.190997
Abstract: Herein, a novel DABCO-based dicationic ionic liquid (bis-DIL) was easily prepared from the sonication of DABCO with 1,3-dichloro-2-propanol and then characterized by several techniques. Thereafter, under the ultimate green conditions, the performance of the bis-DIL… read more here.
Keywords: dabco; amino arylidenethiazol; arylidenethiazol ones; dabco based ... See more keywords
Binuclear Triphenylantimony(V) Catecholates through N-Donor Linkers: Structural Features and Redox Properties
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DOI: 10.3390/molecules27196484
Abstract: A series of binuclear triphenylantimony(V) bis-catecholato complexes 1–11 of the type (Cat)Ph3Sb-linker-SbPh3(Cat) was prepared by a reaction of the corresponding mononuclear catecholates (Cat)SbPh3 with a neutral bidentate donor linker ligands pyrazine (Pyr), 4,4′-dipyridyl (Bipy), bis-(pyridine-4-yl)-disulfide… read more here.
Keywords: dabco; bipy; dbcat linker; cat ... See more keywords