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   Articles with "dach" as a keyword



Achieving Highly Reversible and Dendrite‐Free Zinc Anode Using Dual‐Function 1,2‐DACH Electrolyte Additive Via Reconstructed Solvation Structure and In Situ Interfacial Protective Layer

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recommendations! Published in 2025 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202513335

Abstract: Metallic zinc anode always suffers from dendritic growth and side reactions induced by active H2O in aqueous electrolytes, which severely restrict its practical application in aqueous zinc ion batteries (AZIBs). Herein, cis‐1,2‐cyclohexanediamine (1,2‐DACH) as a… read more here.

Keywords: dach; electrolyte additive; dendrite free; zinc ... See more keywords

1,2- trans -Diaminocyclohexane (DACH) in Asymmetric Catalysis: Nearing Fifty Years of Faithful Service and Counting

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recommendations! Published in 2024 at "Synthesis"

DOI: 10.1055/s-0042-1751582

Abstract: This review highlights the use of DACH as a versatile ligand in catalytic asymmetric transformations providing mechanistic rationales and relevant comments presented in chronological order for each of the 21 reaction types with references up… read more here.

Keywords: alkenes catalytic; dach; addition; reactions catalytic ... See more keywords

Improving activity of anticancer oxalipalladium analog by the modification of oxalate group with isopentylglycine

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recommendations! Published in 2017 at "Journal of Coordination Chemistry"

DOI: 10.1080/00958972.2017.1395417

Abstract: Abstract In this article, we describe the influence of structure on biological behavior of amino acid-Pd complex and compare it with oxalipalladium. A new water-soluble oxalipalladium analog with formula of [Pd(DACH)(isopentylgly)](NO3), where DACH is 1R,2R-diaminocyclohexane,… read more here.

Keywords: amino acid; dna; analog; dach ... See more keywords

Antibacterial Activities of Transition Metal complexes of Mesocyclic Amidine 1,4-diazacycloheptane (DACH)

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recommendations! Published in 2019 at "Open Chemistry"

DOI: 10.1515/chem-2019-0108

Abstract: Abstract The titled compound 1,4-diazacycloheptane have vibrational freedom which allows it to coordinate to metal through 1st and 4th positions. Copper (II) and Nickel (II) complexes of DACH were prepared and characterized through UV-Visible, FT-IR,… read more here.

Keywords: activities transition; metal; metal complexes; dach ... See more keywords

Designed Syntheses of Three {Ni6PW9}-Based Polyoxometalates, from Isolated Cluster to Cluster-Organic Helical Chain

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recommendations! Published in 2022 at "Molecules"

DOI: 10.3390/molecules27134295

Abstract: Three new hexa-Ni-substituted Keggin-type polyoxometalates (POMs), [Ni6(OH)3- (DACH)3(H2O)6(PW9O34)]·31H2O (1), [Ni(DACH)2][Ni6(OH)3(DACH)3(HMIP)2(H2O)2(PW9O34)]·56 H2O (2), and [Ni(DACH)2][Ni6(OH)3(DACH)2(AP)(H2O)5(PW9O34)]·2H2O (3) (DACH = 1,2-Diami- nocyclohexane, MIP = 5-Methylisophthalate, AP = Adipate) were successfully made in the presence of DACH under hydrothermal… read more here.

Keywords: cluster organic; pom cluster; dach; cluster ... See more keywords