Regiocontrolled halogen dance of 2,5-dibromopyrroles using equilibrium between dibromopyrrolyllithiums.
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DOI: 10.1039/d2cc06373e
Abstract: A regiocontrolled halogen dance reaction of 2,5-dibromopyrroles is described. An N,N-dimethylsulfamoyl group on the pyrrole nitrogen was especially effective for facilitating interconversion of the resulting 2,3- and 2,4-dibromopyrrolyllithiums, rendering the smooth halogen dance reaction. This… read more here.
Keywords: halogen; regiocontrolled halogen; halogen dance; dance dibromopyrroles ... See more keywords