Concise Enantioselective Total Synthesis of Daphenylline Enabled by an Intramolecular Oxidative Dearomatization.
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DOI: 10.1021/jacs.2c01674
Abstract: Daphenylline is a structurally unique member of the triterpenoid Daphniphyllum natural alkaloids, which exhibit intriguing biological activities. Six total syntheses have been reported, five of which utilize aromatization approaches. Herein, we report a concise protecting-group-free… read more here.
Keywords: concise; intramolecular oxidative; oxidative dearomatization; total synthesis ... See more keywords