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Published in 2020 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2020.01.031
Abstract: Treatment of a bulky dbhmp-bian ligand (dbhmp-bian = = 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) by 1 equiv. of LiAlH4 or mixture of 3/4 equiv. LiAlH4 and 1/3 eqiuv. AlCl3 in tetrahydrofuran results in new hydrides [(dbhmp-bian)AlH2(THF)]-[Li(THF)4]+ and (dbhmp-bian)AlH(THF), respectively. Both complexes were…
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Keywords:
dbhmp bian;
new aluminum;
synthesis new;
step synthesis ... See more keywords