The method for synthesis of 2-sulfanyl closo-decaborate anion and its S-alkyl and S-acyl derivatives
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2016.11.035
Abstract: Abstract A two-stage method for preparation of the sulfanyl derivative of closo-decaborate anion (n-Bu4N)2[2-B10H9SH]2- (1) is worked out. At the first stage, the [2-B10H9SC(NMe2)2]- (2) or the [2-B10H9SCHNMe2]- (3) derivative is obtained by the reaction… read more here.
Keywords: decaborate anion; closo decaborate; sulfanyl;
New approaches to the functionalization of the 1-carba-closo-decaborate anion.
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DOI: 10.1039/d1cc06395b
Abstract: Two new approaches to the functionalization of the 1-carba-closo-decaborate anion [1-CB9H10]- at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and… read more here.
Keywords: new approaches; closo decaborate; approaches functionalization; decaborate anion ... See more keywords
Non-Covalent Interactions in the Crystal Structures of Perbrominated Sulfonium Derivatives of the closo-Decaborate Anion
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DOI: 10.3390/ijms231912022
Abstract: A new series of compounds based on perbrominated disubstituted sulfonium derivatives of the closo-decaborate anion (n-Bu4N)[2-B10Br9SR2] (R = n-Pr, i-Pr, n-Bu, n-C8H17, n-C12H25, n-C18H37) was obtained, characterised by modern physicochemical methods of analysis. According to… read more here.
Keywords: closo decaborate; decaborate anion; non covalent; derivatives closo ... See more keywords