Microwave-assisted decarbonylation of biomass-derived aldehydes using Pd-doped hydrotalcites.
Sign Up to like & getrecommendations! Published in 2019 at "ChemSusChem"
DOI: 10.1002/cssc.201901934
Abstract: Catalytic decarbonylation is an underexplored strategy for deoxygenation of biomass-derived aldehydes due to a lack of lowcost and robust heterogeneous catalysts able to operate in benign solvents. A family of Pd functionalized hydrotalcites (Pd-HTs) were… read more here.
Keywords: biomass; derived aldehydes; biomass derived; microwave assisted ... See more keywords
Photo-redox coupled Co-pincer complexes for efficient decarbonylation of aryl carbonyls: A quantum chemical investigation
Sign Up to like & getrecommendations! Published in 2021 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2021.111553
Abstract: Abstract Catalytic decarbonylation of aryl carbonyls is a challenging task. Although some precious metal based catalysts have been developed, Earth abundant transition metal based decarbonylating catalysts are yet to be realized. Very recently, Co(I) pincer… read more here.
Keywords: decarbonylation aryl; aryl carbonyls; decarbonylation; efficient decarbonylation ... See more keywords
Decarbonylation and hydrogenation reaction of furfural on Pd/Cu(111) surface
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Fuel Chemistry and Technology"
DOI: 10.1016/s1872-5813(17)30008-7
Abstract: Abstract The adsorption behavior, decarbonylation and hydrogenation reaction mechanisms of furfural on best Pd/Cu(111) bimetallic model were investigated by density functional theory method. The results show that the initial adsorption at O3-Pd-top and O7-Cu-hcp site… read more here.
Keywords: hydrogenation reaction; reaction furfural; decarbonylation hydrogenation; reaction ... See more keywords
Selective Production of Furan from Gas-Phase Furfural Decarbonylation on Ni-MgO Catalysts
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b06155
Abstract: A series of Ni-MgO catalysts (Ni/Mg molar ratio: 0.1–0.3), prepared by a coprecipitation-calcination-reduction methodology, was characterized and evaluated in the gas-phase hydrogenation of furfural. In all cases, after reduction at 500 °C, nickel species were… read more here.
Keywords: mgo; gas phase; decarbonylation; mgo catalysts ... See more keywords
Rhodium-Catalyzed Deuterated Tsuji-Wilkinson Decarbonylation of Aldehydes with Deuterium Oxide.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c04422
Abstract: The recent surge in the applications of deuterated drug candidates has rendered an urgent need for diverse deuterium labeling techniques. Herein, an efficient Rh-catalyzed deuterated Tsuji-Wilkinson decarbonylation of naturally available aldehydes with D2O is developed.… read more here.
Keywords: catalyzed deuterated; wilkinson decarbonylation; deuterium; tsuji wilkinson ... See more keywords
Catalytic decarbonylation of stearic acid to hydrocarbons over activated carbon-supported nickel
Sign Up to like & getrecommendations! Published in 2018 at "Sustainable Energy and Fuels"
DOI: 10.1039/c8se00189h
Abstract: In this study, the deoxygenation of stearic acid over a series of Ni-based catalysts in the absence of hydrogen and solvents was investigated. Ni/Al2O3, Ni/TiO2, Ni/ZrO2, and Ni/AC (activated carbon) were synthesized using the wetness… read more here.
Keywords: deoxygenation; stearic acid; decarbonylation; acid ... See more keywords
Recent advancements on decarbonylation reactions assisted by Ru-complexes: Synthetic and mechanistic approach.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00241h
Abstract: This frontier article covers the recent advancements in ruthenium complex catalysed decarbonylation reactions of different types of carbonyl compounds and provides a direction towards the mechanistic understanding. The mechanistic pathways provide new strategies for the… read more here.
Keywords: advancements decarbonylation; recent advancements; ruthenium; reactions assisted ... See more keywords