Palladium-Catalyzed Decarbonylative Alkylation of Acyl Fluorides.
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DOI: 10.1021/acs.orglett.0c00542
Abstract: Palladium-catalyzed decarbonylative alkylation reactions of acyl fluorides have been developed using alkylboranes having β-hydrogens. A wide range of functional groups were well tolerated, even at the high temperature required for decarbonylation. This protocol provides a… read more here.
Keywords: catalyzed decarbonylative; acyl fluorides; palladium catalyzed; decarbonylative alkylation ... See more keywords
Ru(II)-Catalyzed Decarbonylative Alkylation and Annulations of Benzaldehydes with Iodonium Ylides under Chelation Assistance.
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DOI: 10.1021/acs.orglett.2c01843
Abstract: A Ru(II)-catalyzed decarbonylative alkylation and annulation of salicylaldehydes and 2-aminobenzaldehydes with iodonium ylides has been developed for the synthesis of dibenzo[b,d]furans and NH-free carbazolones. The reaction proceeds smoothly under mild conditions with a low catalyst… read more here.
Keywords: alkylation annulations; catalyzed decarbonylative; iodonium ylides; decarbonylative alkylation ... See more keywords