Articles with "decarboxylative alkenylation" as a keyword



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Nickel-Catalyzed Decarboxylative Alkenylation of Anhydrides with Vinyl Triflates or Halides.

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Published in 2019 at "Organic letters"

DOI: 10.1021/acs.orglett.9b01048

Abstract: Decarboxylative cross-coupling of aliphatic acid anhydrides with vinyl triflates or halides was accomplished via nickel catalysis. This methodology works well with a broad array of substrates and features abundant functional group tolerance. Notably, our approach… read more here.

Keywords: anhydrides vinyl; catalyzed decarboxylative; decarboxylative alkenylation; vinyl triflates ... See more keywords

Decarboxylative Alkenylation

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Published in 2017 at "Nature"

DOI: 10.1038/nature22307

Abstract: Olefin chemistry, through pericyclic reactions, polymerizations, oxidations, or reductions, has an essential role in the manipulation of organic matter. Despite its importance, olefin synthesis still relies largely on chemistry introduced more than three decades ago,… read more here.

Keywords: geometry; chemistry; decarboxylative alkenylation;