Chemoenzymatic Hunsdiecker-Type Decarboxylative Bromination of Cinnamic Acids
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DOI: 10.1021/acscatal.2c00485
Abstract: In this contribution, we report chemoenzymatic bromodecarboxylation (Hunsdiecker-type) of α,ß-unsaturated carboxylic acids. The extraordinarily robust chloroperoxidase from Curvularia inaequalis (CiVCPO) generated hypobromite from H2O2 and bromide, which then spontaneously reacted with a broad range of… read more here.
Keywords: type decarboxylative; hunsdiecker; decarboxylative bromination; chemoenzymatic hunsdiecker ... See more keywords
Transition-metal-free decarboxylative bromination of aromatic carboxylic acids† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc01016a
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DOI: 10.1039/c8sc01016a
Abstract: Aromatic acids are converted into aryl bromides simply and efficiently via decarboxylation providing new depth and insight into Hunsdiecker-type reactivity. read more here.
Keywords: transition metal; aromatic carboxylic; bromination aromatic; metal free ... See more keywords