Stilbene synthesis through decarboxylative cross-coupling of substituted cinnamic acids with aryl halides
Sign Up to like & getrecommendations! Published in 2018 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2018.04.031
Abstract: Abstract The Pd-catalyzed decarboxylative cross-coupling reaction between cinnamic acid and aryl iodide derivatives was studied using both homogeneous and heterogeneous Pd-catalysts. It was demonstrated that simple Pd(OAc)2 can catalyze this reaction with useful to high… read more here.
Keywords: coupling substituted; decarboxylative cross; stilbene synthesis; cross coupling ... See more keywords
A Practically Unified Electrochemical Strategy for Ni-Catalyzed Decarboxylative Cross-Coupling of Aryl Trimethylammonium Salts.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00408
Abstract: By merging electrocatalysis and nickel catalysis, a unified strategy has been successfully applied to achieve the decarboxylative cross-coupling of four types of α-oxocarboxylic acids and their derivatives with aryl trimethylammonium salts under mild conditions. Our… read more here.
Keywords: cross coupling; decarboxylative cross; trimethylammonium salts; strategy ... See more keywords
Palladium-Catalyzed (3 + 2) Annulation of Aromatic Acids by C(sp3)-H Olefination and Decarboxylative Cross-Coupling Reaction.
Sign Up to like & getrecommendations! Published in 2024 at "Organic letters"
DOI: 10.1021/acs.orglett.3c04177
Abstract: A palladium-catalyzed (3 + 2) annulation of 2-methylbenzoic acid with maleimide using Ac-Leu-OH as a powerful ligand has been reported. Through a site-selective γ-C(sp3)-H olefination reaction and a sequential decarboxylative cross-coupling reaction, a five-membered cyclic… read more here.
Keywords: reaction; palladium catalyzed; cross coupling; decarboxylative cross ... See more keywords
Nickel-Catalyzed Reductive Arylalkylation via a Migratory Insertion/Decarboxylative Cross-Coupling Cascade.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02870
Abstract: Reported is a nickel-catalyzed reductive arylalkylation of unactivated alkenes tethered to aryl iodides with redox active N-hydroxyphthalimide esters as the alkyl source through successful merging of migratory insertion and decarboxylative cross-coupling in a cascade. This… read more here.
Keywords: migratory insertion; insertion decarboxylative; decarboxylative cross; reductive arylalkylation ... See more keywords
Decarboxylative Cross-Acyl Coupling of Carboxylic Acids with Aldehydes Enabled by Nickel/Photoredox Catalysis.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c00372
Abstract: We present a general method for accessing unsymmetrical alkyl-aryl and alkyl-alkyl ketones via nickel/photoredox-catalyzed decarboxylative cross-acyl coupling reactions between carboxylic acids and aldehydes without the need for an additional preactivation procedure. Specifically, by using the… read more here.
Keywords: decarboxylative cross; nickel photoredox; acyl coupling; cross acyl ... See more keywords
Nickel-catalyzed decarboxylative cross-coupling of indole-3-acetic acids with aryl bromides by convergent paired electrolysis.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02641d
Abstract: Herein, nickel-catalyzed decarboxylative cross-coupling of indole-3-acetic acids with aryl bromides by convergent paired electrolysis was developed in an undivided cell. This protocol features good functional group tolerance, and is chemical redox agent- and sacrificial electrode-free.… read more here.
Keywords: indole acetic; cross coupling; nickel catalyzed; coupling indole ... See more keywords
Synthesis of peri-Diarylated Naphthalimides via Double Decarboxylative Cross-Coupling Reaction
Sign Up to like & getrecommendations! Published in 2019 at "Synthesis"
DOI: 10.1055/s-0037-1611762
Abstract: A facile method for the synthesis of peri-diarylated naphthalimides was developed by using a palladium-catalyzed double decarboxylative cross-coupling reaction. The present work offers a convenient approach for tuning the optical properties of naphthalimide derivatives. read more here.
Keywords: cross coupling; double decarboxylative; synthesis peri; peri diarylated ... See more keywords