Deciphering the mechanism of the nickel-catalyzed hydroalkoxylation reaction: A combined experimental and computational study
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.7b00616
Abstract: ABSTRACT: The [Ni(COD)2]/P P-catalysed hydroalkoxylation of butadiene to form butenyl ethers is studied mechanistically, where P P = 1,4-bis(diphenylphosphino)butane (dppb) and 1,2-bis(diphenylphosphinomethyl)benzene (dppmb). Experimental studies suggest the intermediacy of [(P P)Ni(0)(butadiene)] and [(P P)Ni(II)(allyl)] intermediates… read more here.
Keywords: hydroalkoxylation; deciphering mechanism; hydroalkoxylation reaction; nickel catalyzed ... See more keywords
Deciphering the mechanism of copper-catalyzed N-arylation between aryl halides and nitriles: a DFT study
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj03860d
Abstract: The mechanism of the CuI/DMEDA-catalyzed tandem hydrolysis/N-arylation of benzonitrile with aryl iodide was studied using the DFT method. read more here.
Keywords: mechanism copper; mechanism; arylation; deciphering mechanism ... See more keywords