Synthesis of Dialkenyl-Substituted Double-Decker Silsesquioxanes as Precursors for Linear Copolymeric Systems
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Inorganic and Organometallic Polymers and Materials"
DOI: 10.1007/s10904-017-0746-y
Abstract: In this paper, we report an efficient synthetic route for dialkenyl-substituted double-decker silsesquioxane derivatives as difunctional reagents for further applications. This study concerns synthesis of allyl, hex-5-enyl- and dec-9-enyl-double-decker silsesquioxanes obtained via condensation and hydrosilylation… read more here.
Keywords: substituted double; decker silsesquioxanes; dialkenyl substituted; double decker ... See more keywords
N-Heterocyclic carbene-based ruthenium-hydride catalysts for the synthesis of unsymmetrically functionalized double-decker silsesquioxanes.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc01316k
Abstract: Ruthenium-N-heterocyclic carbene complexes with the generic formula [RuHCl(CO)(NHC)(PCy3)] exhibit a high catalytic activity toward the (E)-selective silylative coupling of divinyl-substituted double-decker silsesquioxanes with two distinctly substituted styrenes. This process leads to a novel class of… read more here.
Keywords: ruthenium; decker silsesquioxanes; heterocyclic carbene; double decker ... See more keywords