The catalytic activities and magnetic behaviours of rare μ3-chlorido and μ1,1,1-azido bridged defective dicubane tetranuclear Mn(ii) complexes.
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DOI: 10.1039/c9dt01567a
Abstract: Reaction of Mn(ii) salts with a flexidentate Mannich base ligand, N,N'-dimethyl-N,N'-bis(2-hydroxy-3-methoxy-5-methylbenzyl)ethylenediamine (H2L) in the presence of chloride or azide ions yielded two new tetranuclear complexes, [Mn4L2(μ3-Cl)2Cl2] (1) and [Mn4L2(μ1,1,1-N3)2(N3)2] (2). Single crystal X-ray structural analyses… read more here.
Keywords: activities magnetic; tetranuclear complexes; defective dicubane; tetranuclear ... See more keywords