Rhodium(I)-Catalyzed Defluorinative Coupling of Boronic Acids with Monofluoroalkenes.
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DOI: 10.1021/acs.orglett.2c02294
Abstract: We herein describe a highly selective Rh(I)-catalyzed defluorinative coupling of boronic acids with (E)-β-monofluoroacrylates. In contrast to previous methods, the trisubstituted (Z)-alkene products were obtained in excellent dr with an inversion of double bond geometry.… read more here.
Keywords: boronic acids; catalyzed defluorinative; defluorinative coupling; coupling boronic ... See more keywords