Chromium-Catalyzed Defluorinative Reductive Coupling of Aldehydes with gem-Difluoroalkenes.
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DOI: 10.1021/acs.orglett.3c00016
Abstract: Herein, a mild and convenient defluorinative reductive cross coupling of gem-difluoroalkenes with aliphatic aldehydes has been developed to afford diverse silyl-protected β-fluorinated allylic alcohols. The reaction is operationally simple and shows good functional group tolerance… read more here.
Keywords: catalyzed defluorinative; defluorinative reductive; gem difluoroalkenes; reductive coupling ... See more keywords