On-Surface Intramolecular Dehalogenation of Vicinal Dibromides for the Direct Formation of C–C Double Bonds
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.9b09713
Abstract: Intramolecular dehalogenation reaction as an essential step is generally involved in the deprotection of carbon-carbon double bonds in solution chemistry. However, harsh reaction conditions often limit the functional-group compatibility and cause the selectivity problems. In… read more here.
Keywords: dehalogenation; intramolecular dehalogenation; chemistry; surface intramolecular ... See more keywords
Dehalogenation of vicinal dihalo compounds by 1,1'-bis(trimethylsilyl)-1H,1'H-4,4'-bipyridinylidene for giving alkenes and alkynes in a salt-free manner.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc07377a
Abstract: We report a transition metal-free dehalogenation of vicinal dihalo compounds by 1,1'-bis(trimethylsilyl)-1H,1'H-4,4'-bipyridinylidene (1) under mild conditions, in which trimethylsilyl halide and 4,4'-bipyridine were generated as byproducts. The synthetic protocol for this dehalogenation reaction was effective… read more here.
Keywords: vicinal dihalo; bis trimethylsilyl; dihalo compounds; trimethylsilyl bipyridinylidene ... See more keywords