Mechanochemical Dehalogenative Deuteration of Alkyl Halides Through Piezoelectric Catalysis Initiated by a Single‐Electron Oxidation Strategy
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DOI: 10.1002/advs.202515449
Abstract: Deuterium labeling is extensively utilized across various scientific disciplines. The dehalogenative deuteration of organic halides offers a promising approach for achieving deuterium labeling. However, existing methods for dehalogenative deuteration primarily focus on sp2‐hybridized aryl halides,… read more here.
Keywords: deuteration; dehalogenative deuteration; alkyl halides; single electron ... See more keywords
Photo-induced dehalogenative deuteration and elimination of alkyl halides enabled by phosphine-mediated halogen-atom transfer
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DOI: 10.1039/d5sc00026b
Abstract: Dehalogenative deuteration of organic halides is an efficient and straightforward method for incorporating deuterium atoms at specific locations within target molecules. However, utilizing organic halides in photoredox chemistry, particularly unactivated alkyl halides, presents challenges due… read more here.
Keywords: alkyl; alkyl halides; halogen atom; dehalogenative deuteration ... See more keywords