Thiocyanate radical mediated dehydration of aldoximes with visible light and air.
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DOI: 10.1039/c9cc05354a
Abstract: We developed a new means of activating aldoximes by an in situ generated thiocyanate radical from ammonium thiocyanate and molecular oxygen at room temperature. With a catalytic amount of organic dye aizenuranine as the photocatalyst,… read more here.
Keywords: mediated dehydration; thiocyanate radical; dehydration aldoximes; visible light ... See more keywords
SO2F2-Promoted Dehydration of Aldoximes: A Rapid and Simple Access to Nitriles
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DOI: 10.1055/s-0037-1611840
Abstract: A rapid, simple and mild process for the dehydration of aldoximes to give the corresponding nitriles, which utilizes SO2F2 as an efficient reagent, has been developed. A variety of (hetero)arene, alkene, alkyne and aliphatic aldoximes… read more here.
Keywords: dehydration aldoximes; access nitriles; rapid simple; so2f2 promoted ... See more keywords