One pot conversion of acetyl chloride to dehydroacetic acid and its coordination in a ruthenium(II) arene complex
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.08.003
Abstract: Abstract The reaction of [(η6-p-cymene)RuCl(κ2N,O- l- serinate)], 1, with CH3C(O)Cl/NEt3, in chloroform at reflux temperature, led to the serendipitous isolation of the dehydroacetate complex [(η6-p-cymene)RuCl(κ2O,O′-dha)], 2, in low amount. Then, dehydroacetic acid (dhaH) was prepared… read more here.
Keywords: one pot; chemistry; acetyl chloride; cymene ... See more keywords
Modification of insulin amyloid aggregation by Zr phthalocyanines functionalized with dehydroacetic acid derivatives
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DOI: 10.1371/journal.pone.0243904
Abstract: Amyloid fibrils are widely studied both as target in conformational disorders and as basis for the development of protein-based functional materials. The three Zr phthalocyanines bearing dehydroacetic acid residue (PcZr(L1)2) and its condensed derivatives (PcZr(L2)2… read more here.
Keywords: insulin; aggregation; pczr; spectroscopy ... See more keywords