Sustainable preparation of aminosilane monomers, oligomers, and polymers through Si-N dehydrocoupling catalysis.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc07092h
Abstract: This article covers historical and recent efforts to catalyse the dehydrocoupling of amines and silanes, a direct method for Si-N bond formation that offers hydrogen as a byproduct. In some applications, this transformation can be… read more here.
Keywords: aminosilane monomers; aminosilane; preparation aminosilane; dehydrocoupling catalysis ... See more keywords
Phosphorus-containing polycarbosilazanes: synthesis via dehydrocoupling catalysis and flame-retardant properties.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt03172e
Abstract: The barium complex [Ba{N(SiMe3)2}2]2 has been used to catalyse the dehydropolymerisation of the phosphine-functionalised hydrosilane 4-Ph2P-C6H4SiH3 (A) with the α,ω-diamine 1,4-(CH2NHMe)2-C6H4 (C), for the production of -[Si(4-C6H4PPh2)H-N(Me)CH2-C6H4-CH2N(Me)]n- polycarbosilazanes that contain dangling phosphino groups along the… read more here.
Keywords: synthesis via; phosphorus containing; dehydrocoupling catalysis; polycarbosilazanes synthesis ... See more keywords