Acceptorless Dehydrogenation of Alcohols Catalyzed by CuI N‐Heterocycle Thiolate Complexes
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201601459
Abstract: CuI N‐heterocycle thiolate clusters efficiently catalyze the acceptorless dehydrogenation of alcohols at 70 °C. A variety of secondary/primary benzylic, allylic, and aliphatic alcohols are dehydrogenated to the corresponding ketones and aldehydes in high yields of isolated… read more here.
Keywords: cui heterocycle; acceptorless dehydrogenation; dehydrogenation alcohols; heterocycle thiolate ... See more keywords
Acceptorless dehydrogenation of alcohols to carboxylic acids by palladium nanoparticles supported on NiO: delving into metal-support cooperation in catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01311h
Abstract: In this work, we have developed a simple NiO-supported Pd nanocatalyst (Pd@NiO) for oxidant-free dehydrogenative oxidation of primary alcohols to carboxylic acids along with hydrogen gas as a byproduct. The catalyst has been characterized by… read more here.
Keywords: alcohols carboxylic; acceptorless dehydrogenation; nanoparticles supported; dehydrogenation alcohols ... See more keywords