Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex.
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DOI: 10.1039/c7dt01499f
Abstract: The reaction of a Cp*Ir(iii) phosphoramidate complex with secondary amines gives amine, imine-bound Cp*Ir(iii) hydride complexes resulting from amine dehydrogenation. These well-characterized species could serve as models of relevant intermediates that have been proposed in… read more here.
Keywords: iii phosphoramidate; cyclic amines; dehydrogenation cyclic; phosphoramidate complex ... See more keywords
Room temperature catalytic dehydrogenation of cyclic amines with the liberation of H2 using water as a solvent
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DOI: 10.1039/c9gc00201d
Abstract: Catalytic dehydrogenation of cyclic amines, in particular partially saturated N-heterocycles to N-heterocyclic arenes, with the removal of molecular hydrogen as the sole byproduct in water is reported. This dehydrogenation reaction proceeds smoothly under very mild… read more here.
Keywords: cyclic amines; dehydrogenation; water; dehydrogenation cyclic ... See more keywords