Metal-ligand cooperative κ1-N-pyrazolate Cp*RhIII-catalysts for dehydrogenation of dimethylamine-borane at room temperature.
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DOI: 10.1039/d1dt01705e
Abstract: 3,5-Dimethylpyrazole (Pz*H) in well-defined Cp*RhIII (Cp* = 1,2,3,4,5-pentamethylcyclopentadienyl) complexes, or as an additive to [Cp*RhCl2]2 enhances catalytic activity in the dehydrogenation of dimethylamine-borane (DMAB) at room-temperature. Mechanistic studies indicate that the Lewis acidic RhIII-centre and… read more here.
Keywords: rhiii; borane; dimethylamine borane; room temperature ... See more keywords