A Diaminopropane Diolefin Ru(0) Complex Catalyzes Hydrogenation and Dehydrogenation Reactions
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DOI: 10.1002/cctc.201901739
Abstract: New ruthenium (0) complexes with a cooperative diolefin diaminopropane (DAP) or the dehydrogenated iminopropenamide ligand (IPA) were synthesized for comparison with their diaminoethane (DAE)/ diazadiene (DAD) ruthenium analogues. These DAP/IPA complexes are efficient catalysts in… read more here.
Keywords: dehydrogenation reactions; diolefin; hydrogenation; diaminopropane diolefin ... See more keywords
Metallacyclopropene structures identified by IRMPD spectroscopic investigation of the dehydrogenation reactions of Ta+ and TaO+ with ethene
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Mass Spectrometry"
DOI: 10.1016/j.ijms.2019.04.005
Abstract: Abstract Species formed in the reactions of Ta+ and TaO+ with ethene are examined spectroscopically using infrared multiple photon dissociation (IRMPD) action spectroscopy. Ta+, TaC2H2+, and TaO+ are all observed to dehydrogenate ethene yielding [Ta,2C,2H]+,… read more here.
Keywords: dehydrogenation reactions; reactions tao; tao ethene; metallacyclopropene structures ... See more keywords
Metal-catalyzed hydrogenation and dehydrogenation reactions for efficient hydrogen storage
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DOI: 10.1016/j.tet.2020.130946
Abstract: Abstract Hydrogen is widely considered an ideal energy source from the viewpoint of sustainability. However, as hydrogen is a gas under ambient conditions and needs to be handled with care, the development of safe and… read more here.
Keywords: dehydrogenation reactions; hydrogen storage; efficient hydrogen; hydrogen ... See more keywords
Iron-based nanocatalyst for the acceptorless dehydrogenation reactions
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DOI: 10.1038/s41467-017-01603-3
Abstract: Development of sustainable catalytic systems for fundamentally important synthetic transformations and energy storage applications is an intellectually stimulating challenge. Catalytic dehydrogenation of feedstock chemicals, such as alcohols and amines to value-added products with the concomitant… read more here.
Keywords: dehydrogenation reactions; dehydrogenation; catalyst; iron based ... See more keywords