Dehydrogenative amide synthesis from alcohols and amines utilizing N-heterocyclic carbene-based ruthenium complexes as efficient catalysts: The influence of catalyst loadings, ancillary and added ligands
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114979
Abstract: Abstract The metal-catalyzed dehydrogenative coupling of alcohols and amines to access amides has been recognized as an atom-economic and environmental-friendly process. Apart from the formation of the amide products, three other kinds of compounds (esters,… read more here.
Keywords: alcohols amines; carbene based; added nhc; dehydrogenative amide ... See more keywords
Rethinking the Dehydrogenative Amide Synthesis
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DOI: 10.1021/acscatal.7b02415
Abstract: This paper is concerned with the mechanism of the catalytic dehydrogenative coupling of primary alcohols with amines; it addresses the question on what happens to the aldehyde produced in the catalytic solution upon dehydrogenation of… read more here.
Keywords: amide synthesis; rethinking dehydrogenative; dehydrogenative amide;