Palladium‐Catalyzed Dehydrogenative Cross‐Coupling Reactions of Hydrosilanes: Facile Synthesis of Silanols and Silyl Ethers
Sign Up to like & getrecommendations! Published in 2024 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202400471
Abstract: We present an efficient palladium‐catalyzed strategy that ingeniously realizes dehydrogenative cross‐coupling reactions between silanes and an oxygen‐containing functional groups (alcohols, phenols, and water) to generate the corresponding silyl ethers and silanols in moderate to high… read more here.
Keywords: dehydrogenative cross; cross coupling; palladium catalyzed; coupling reactions ... See more keywords
Chemoselective Catalytic Dehydrogenative Cross-Coupling of 2-Acylimidazoles: Mechanistic Investigations and Synthetic Scope
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DOI: 10.1021/acscatal.8b02361
Abstract: Chemoselective iron-catalyzed dehydrogenative cross-coupling using 2-acylimidazoles is described. The addition of a phosphine oxide ligand substantially facilitated the generation of tert-butoxy radicals from di-tert-butyl peroxide, allowing for efficient benzylic C–H bond cleavage under mild conditions.… read more here.
Keywords: dehydrogenative cross; chemoselective catalytic; cross; coupling acylimidazoles ... See more keywords
Catalytic Cascade Dehydrogenative Cross-Coupling of BH/CH and BH/NH: One-Pot Process to Carborano-Isoquinolinone.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b06204
Abstract: A proof-of-principle study of cascade dehydrogenative cross-coupling of carboranyl carboxylic acid with readily available benzamide has been achieved, resulting in the facile synthesis of previously inaccessible carborano-isoquinolinone derivatives in a simple one-pot process, in which… read more here.
Keywords: dehydrogenative cross; cascade dehydrogenative; cross; one pot ... See more keywords
Dehydrogenative cross-coupling of o-carborane with thiophenes via Ir-catalyzed regioselective cage B-H and C(sp2)-H activation.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc01485f
Abstract: Ir-Catalyzed -COOH directed site-selective B-H/C-H dehydrogenative cross-coupling of o-carborane with thiophenes has been achieved for the first time. Without any pre-functionalization, carboranyl carboxylic acids and thiophenes can serve as suitable coupling partners, resulting in the… read more here.
Keywords: dehydrogenative cross; carborane thiophenes; cross coupling; coupling carborane ... See more keywords
Transition metal catalyzed selective B(3)-H or B(4)-H amination of o-carboranes via dehydrogenative BH/NH cross-coupling.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02852b
Abstract: A unique approach to vertex-selective catalytic B-H amination at either the B(3)- or B(4)-position in o-carboranes has been developed. Using different transition metal catalysts, dehydrogenative BH/NH cross-coupling of o-carboranes and free amines has been achieved,… read more here.
Keywords: amination; cross coupling; transition metal; dehydrogenative cross ... See more keywords
Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons
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DOI: 10.1039/d4qo01641f
Abstract: An FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant. read more here.
Keywords: modular dehydrogenative; cross nucleophile; dehydrogenative cross; construction ... See more keywords