Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms.
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DOI: 10.1039/c7dt04253a
Abstract: The behavior of the complex (H2L)CoCl2, where H2L is a bis-(pyrazol-3-yl)pyridine, towards Brønsted bases is studied, to evaluate peripheral NH deprotonation as a route to a dianionic pincer ligand on a d7 center. Deprotonation is… read more here.
Keywords: pincer; pyrazolate; dehydrohalogenation proton; pincer ligand ... See more keywords