Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane
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DOI: 10.1039/d2ra04955d
Abstract: The dehydropolymerisation of phenylsilane is investigated using group 4 metallocene amide complexes as catalysts. The dinuclear zirconocene amide complex Cp2Zr(NMe2)(μ-Me3SiC3SiMe3)Zr(NMe2)Cp2 (2) (Cp = η5-cyclopentadienyl) shows high activity in dehydrocoupling reactions, producing polyphenylsilanes with molecular weights… read more here.
Keywords: zirconocene amide; dinuclear zirconocene; amide complexes; dehydropolymerisation phenylsilane ... See more keywords