Synthesis, Characterization, and Properties of Poly(aryl)phosphinoboranes Formed via Iron‐Catalyzed Dehydropolymerization
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DOI: 10.1002/macp.201700120
Abstract: The dehydropolymerization of the primary phosphine–boranes, RPH2•BH3 (1a–f) (R = 3,4-(OCH2O)C6H3 (a), Ph (b), p-(CF3O)C6H4 (c), 3,5-(CF3)2C6H3 (d), 2,4,6-(CH3)3C6H2 (e), 2,4,6-tBu3C6H2 (f)) is explored using the precatalyst [CpFe(CO)2OTf] (I) (OTf = OS(O)2CF3), based on the… read more here.
Keywords: dehydropolymerization; properties poly; aryl phosphinoboranes; characterization properties ... See more keywords