Delocalized and localized donating-accepting Mn-C interactions in half-sandwich cyclopentadienyl and pentadienyl complexes.
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DOI: 10.1039/c7dt00499k
Abstract: The widely used cyclopentadienyl (Cp) ligand and the pentadienyl (Pdl) ligand have very similar molecular orbitals (MOs) but they have significantly different chemical behavior. The extensively mixing of the MOs in the Pdl ligand has… read more here.
Keywords: cyclopentadienyl; pentadienyl; pdl ligand; half sandwich ... See more keywords