Dendritic Macromolecules with an Umbrella-Like Stimuli Response.
Sign Up to like & getrecommendations! Published in 2025 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.5c01994
Abstract: We introduce generation-specific thermoresponsive dendrons that undergo reversible, temperature-triggered conformational changes with an "umbrella-like" conformation. Built from sequence-defined polymer segments via chemoselective iterative coupling, where we could independently control the stimulus response within each generational… read more here.
Keywords: dendritic macromolecules; response; umbrella like; macromolecules umbrella ... See more keywords
Crowding for Confinement: Reversible Isomerization of First-Generation Donor-Acceptor Stenhouse Adduct Derivatives in Water Modulated by Thermoresponsive Dendritic Macromolecules
Sign Up to like & getrecommendations! Published in 2024 at "Molecules"
DOI: 10.3390/molecules29215055
Abstract: Mimicking nature, the reversible isomerization of hydrophobic dyes in aqueous solutions is appealing for bio-applications. Here, we report on the reversible isomerization of first-generation solvatochromic donor-acceptor Stenhouse adducts (DASAs) in water within dendritic matrices, realized… read more here.
Keywords: reversible isomerization; dendritic macromolecules; water; dendritic oegs ... See more keywords