L-Proline/CeCl3·7H2O-NaI mediated stereoselective synthesis of α-2-deoxy glycosides from glucal.
Sign Up to like & getrecommendations! Published in 2018 at "Carbohydrate research"
DOI: 10.1016/j.carres.2018.01.003
Abstract: Glucal with different alcohols can be converted into the corresponding 2-deoxy glycosides without Ferrier rearrangement in high yield by treatment with eco friendly transition metal based catalysts [CuCl3·2H2O-NaI (A) or CeCl3·7H2O-NaI (B)] and chiral amine… read more here.
Keywords: cecl3 7h2o; deoxy glycosides; 7h2o nai; ligand proline ... See more keywords
Stereoselective Synthesis of 2-Deoxy Glycosides via Iron Catalysis.
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DOI: 10.1021/acs.orglett.2c04379
Abstract: An Fe-catalyzed 2-deoxy glycosylation method was developed from 3,4-O-carbonate glycals directly at room temperature. This novel approach enabled facile access to alkyl and aryl 2-deoxy glycosides in high yields with exclusive α-stereoselectivity, tolerating various alcohols,… read more here.
Keywords: synthesis deoxy; glycosides via; deoxy glycosides; stereoselective synthesis ... See more keywords