Highly reactive 2-deoxy-2-iodo-D-allo and D-gulo pyranosyl sulfoxide donors ensure β-stereoselective glycosylations with steroidal aglycones
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DOI: 10.1039/c8ra06619a
Abstract: The preparation of well-defined D-xylo and D-ribo glycosides represents a synthetic challenge due to the limited configurational availability of starting materials and the laborious synthesis of homogeneous 2-deoxy-β-glycosidic linkages, in particular that of the sugar-steroid… read more here.
Keywords: highly reactive; reactive deoxy; deoxy iodo; steroidal aglycones ... See more keywords