Molybdenum-Quinone-Catalyzed Deoxygenative Coupling of Aromatic Carbonyl Compounds.
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DOI: 10.1021/acs.orglett.2c03143
Abstract: In the presence of triphenylphosphine as a mild reductant, the use of catalytic amounts of Mo(CO)6 and an ortho-quinone ligand enables the intermolecular reductive coupling of aromatic aldehydes and the intramolecular coupling of aromatic ketones… read more here.
Keywords: molybdenum quinone; catalyzed deoxygenative; deoxygenative coupling; coupling aromatic ... See more keywords
Metal-free deoxygenative coupling of alcohol-derived benzoates and pyridines for small molecules and DNA-encoded libraries synthesis
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc01621d
Abstract: Alcohols are among the most widely occurring functional groups found in naturally abundant, biologically relevant organic compounds, which in many cases are considered feedstock chemicals. Herein, we report a metal-free method for the deoxygenative coupling… read more here.
Keywords: benzoates pyridines; deoxygenative coupling; metal free; alcohol derived ... See more keywords