Ruthenium-Catalyzed Deoxygenative Hydroboration of Carboxylic Acids
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b00900
Abstract: An efficient deoxygenative hydroboration of carboxylic acids to alkyl boronate esters under mild reaction condition is reported. Both aromatic and aliphatic carboxylic acids exhibited excellent reactivities with minimal catalyst load of 0.1 mol % and reactions… read more here.
Keywords: carboxylic acids; hydroboration carboxylic; deoxygenative hydroboration; ruthenium catalyzed ... See more keywords
Cyclic (Alkyl)(amino)carbene Ligand-Promoted Nitro Deoxygenative Hydroboration with Chromium Catalysis: Scope, Mechanism, and Applications.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c12318
Abstract: Transition metal catalysis that utilizes N-heterocyclic carbenes as noninnocent ligands in promoting transformations has not been well studied. We report here a cyclic (alkyl)(amino)carbene (CAAC) ligand-promoted nitro deoxygenative hydroboration with cost-effective chromium catalysis. Using 1… read more here.
Keywords: amino carbene; hydroboration; catalysis; deoxygenative hydroboration ... See more keywords