From Ground-State to Excited-State Activation Modes: Flavin-Dependent "Ene"-Reductases Catalyzed Non-natural Radical Reactions.
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DOI: 10.1021/acs.accounts.4c00129
Abstract: ConspectusEnzymes are desired catalysts for chemical synthesis, because they can be engineered to provide unparalleled levels of efficiency and selectivity. Yet, despite the astonishing array of reactions catalyzed by natural enzymes, many reactivity patterns found… read more here.
Keywords: flavin dependent; radical reactions; dependent ene; ene reductases ... See more keywords