Flavin-Dependent Monooxygenase-Mediated 1,2-Oxazine Construction via Meisenheimer Rearrangement in the Biosynthesis of Paeciloxazine.
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DOI: 10.1021/jacs.2c00881
Abstract: The [1,2]-Meisenheimer rearrangement is well known as the [1,2]-migration of an O-substituted hydroxylamine from a tertiary amine N-oxide, and it is frequently employed in organic synthesis to enforce adjacent carbon oxidation or install a 1,2-oxazine… read more here.
Keywords: meisenheimer rearrangement; rearrangement; dependent monooxygenase; flavin dependent ... See more keywords