Excitation-Wavelength-Dependent Photophysics of d8d8 Di-isocyanide Complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02645
Abstract: Binuclear Rh(I) and Ir(I) TMB (2,5-dimethyl-2,5-diisocyanohexane) and dimen (1,8-diisocyanomenthane) complexes possess dσ*pσ and dπpσ singlet and triplet excited states that can be selectively excited in the visible and UV spectral regions. Using perturbational spin-orbit TDDFT,… read more here.
Keywords: excitation wavelength; wavelength dependent; photophysics d8d8; excitation ... See more keywords
Oxygen-dependent photophysics and photochemistry of prototypical compounds for organic photovoltaics: inhibiting degradation initiated by singlet oxygen at a molecular level.
Sign Up to like & getrecommendations! Published in 2019 at "Methods and applications in fluorescence"
DOI: 10.1088/2050-6120/ab4edc
Abstract: Photo-initiated, oxygen-mediated degradation of the molecules in the active layer of organic photovoltaic, OPV, devices currently limits advances in the development of solar cells. To address this problem systematically and at a molecular level, it… read more here.
Keywords: oxygen; degradation; molecular level; dependent photophysics ... See more keywords