Predicting spatially dependent reaction rate for problem with nonuniform temperature distribution by subgroup method
Sign Up to like & getrecommendations! Published in 2018 at "Annals of Nuclear Energy"
DOI: 10.1016/j.anucene.2017.08.054
Abstract: Abstract The subgroup methods based on partial cross section fit scheme (PXSFS) and simplified partial cross section fit scheme (SPXSFS) are proposed in this paper to treat problems with non-uniform temperature distribution. These methods fit… read more here.
Keywords: subgroup; dependent reaction; temperature distribution; method ... See more keywords
Temperature-dependent reaction rates of quinone-alkene cycloaddition reveal that only entropy determines the rate of SPOCQ reactions.
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DOI: 10.1039/d5sc04275e
Abstract: Second-order rate constants and thermodynamic activation parameters for the strain-promoted oxidation-controlled quinone (SPOCQ) click reaction of an ortho-quinone with various trans-cyclooctene and cyclooctyne reagents were determined by stopped-flow spectroscopic analysis. We substantiate the origin of… read more here.
Keywords: reaction; rate; reaction rates; dependent reaction ... See more keywords