Solvent‐Dependent Reactivity and Photochemistry of Dinuclear and Mononuclear Platinum(IV) Azido Triazaolato Complexes
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DOI: 10.1002/ejic.202100041
Abstract: Abstract Reaction between the platinum(IV) azido complex trans,trans,trans‐[Pt(py)2(N3)2(OH)2] (1) and 1,4‐diphenyl‐2‐butyne‐1,4‐dione 2 in MeCN produces the intermediate peroxide‐bridged dimeric platinum(IV) azido triazolato species (5), which has been characterised by X‐ray crystallography. However, if the reaction… read more here.
Keywords: platinum azido; dependent reactivity; platinum; trans trans ... See more keywords
Iron(II)-α-keto acid complexes of tridentate ligands on gold nanoparticles: the effect of ligand geometry and immobilization on their dioxygen-dependent reactivity.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt02433k
Abstract: Two mononuclear nonheme iron(II)-benzoylformate (BF) complexes [(6Me2-Me-BPA)Fe(BF)](ClO4) (1a) and [(6Me3-TPMM)Fe(BF)](ClO4) (1b) of tridentate nitrogen donor ligands, bis((6-methylpyridin-2-yl)methyl)(N-methyl)amine (6Me2-Me-BPA) and tris(2-(6-methyl)pyridyl)methoxymethane (6Me3-TPMM), were isolated and characterized. The structural characterization of iron(II)-chloro complexes indicates that the ligand… read more here.
Keywords: immobilization; dioxygen; iron; geometry ... See more keywords