Wavelength-dependent rearrangements of an α-dione chromophore: a chemical pearl in a bis(hypersilyl) oyster
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DOI: 10.1039/d4sc00064a
Abstract: The symmetric bissilyl-dione 3 reveals two well-separated n → π* absorption bands at λmax = 637 nm (ε = 140 mol−1 dm3 cm−1) and 317 nm (ε = 2460 mol−1 dm3 cm−1). Whereas excitation of… read more here.
Keywords: dione; wavelength dependent; hypersilyl; dependent rearrangements ... See more keywords