Molecular Rationale for Partitioning between C-H and C-F Bond Activation in Heme-Dependent Tyrosine Hydroxylase.
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DOI: 10.1021/jacs.1c00175
Abstract: The heme-dependent l-tyrosine hydroxylases (TyrHs) in natural product biosynthesis constitute a new enzyme family in contrast to the nonheme iron enzymes for DOPA production. A representative TyrH exhibits dual reactivity of C-H and C-F bond… read more here.
Keywords: bond; dependent tyrosine; tyrosine; bond activation ... See more keywords