Articles with "dependent umpolung" as a keyword



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Metal-Dependent Umpolung Reactivity of Carbenes Derived from Cyclopropenes

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Published in 2019 at "iScience"

DOI: 10.1016/j.isci.2019.04.001

Abstract: Summary Metal carbenes, divalent carbon species, are versatile intermediates that enable novel synthetic pathways. These species exhibit either electrophilic or nucleophilic character, depending on the carbene and metal fragments. Although the metal carbene reactivity is… read more here.

Keywords: carbene reactivity; metal; dependent umpolung; reactivity ... See more keywords