Orthopalladated 1,4-iminonaphthoquinone derivative: Syntheses, redox series, molecular and electronic structures
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DOI: 10.1016/j.ica.2018.12.003
Abstract: Abstract Reaction of 2-((2-(phenylthio)phenyl)amino)-4-((2-(phenylthio)phenyl)imino)naphthalene-1(4H)-one (LH2) that is a N,S-chelating 1,4-iminonaphthoquinone derivative, with [Pd(DMSO)2Cl2] in boiling MeOH promotes an aromatic C H activation reaction affording an orthopalladated iminonaphthoquinone derivative, [PdII(LH−)Cl] (1). The molecular geometries and the… read more here.
Keywords: iminonaphthoquinone derivative; syntheses redox; derivative syntheses; lh2 ... See more keywords