Palladium-Catalyzed Highly Regioselective C6 Arylation of Pyrrolo[2,3-d]pyrimidine Derivatives with Arylboronic Acids.
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DOI: 10.1021/acs.orglett.3c00680
Abstract: A mild and selective C6 arylation strategy for pyrrolo[2,3-d]pyrimidine derivatives with arylboronic acids at room temperature is described. This unified protocol has been achieved by the synergistic combination of Pd(II)/TEMPO catalysis and CF3CO2H promotion under… read more here.
Keywords: derivatives arylboronic; pyrrolo pyrimidine; arylboronic acids; pyrimidine derivatives ... See more keywords