Ru-Catalyzed Isomerization of Achmatowicz Derivatives: A Sustainable Route to Biorenewables and Bioactive Lactones
Sign Up to like & getrecommendations! Published in 2023 at "ACS Catalysis"
DOI: 10.1021/acscatal.2c04867
Abstract: A Ru-catalyzed isomerization of Achmatowicz derivatives that opens unexplored routes to diversify the biogenic furanic platform is reported. The mechanistic insights of this formally redox-neutral intramolecular process were studied computationally and by deuterium labeling. The… read more here.
Keywords: achmatowicz derivatives; derivatives sustainable; isomerization achmatowicz; catalyzed isomerization ... See more keywords
Cinchona derivatives as sustainable and recyclable homogeneous organocatalysts for aza-Markovnikov addition
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DOI: 10.1039/c8nj01277f
Abstract: Three cinchona derivatives have shown remarkable activity to catalyze the aza-Markovnikov addition reaction of N-heterocycles to vinyl esters. The synthesis of aza-Markovnikov adducts possessing valuable biological activity was thoroughly optimized. By studying the ratio of… read more here.
Keywords: markovnikov addition; derivatives sustainable; aza markovnikov; cinchona derivatives ... See more keywords