Palladium(II)-catalyzed intramolecular aminoacetoxylation of sugar derived alkenyl tosylsulfonamide: Total synthesis of l-deoxyallonojirimycin
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DOI: 10.1016/j.tetlet.2016.12.057
Abstract: Abstract Palladium catalyzed intramolecular aminoacetoxylation of d -ribose derived alkenyl tosylsulfonamide to deliver l -deoxyallonojirimycin in an overall yield of 19%. The preliminary screening of l -deoxyallonojirimycin against carbohydrate processing enzymes showed moderate inhibitory activity… read more here.
Keywords: intramolecular aminoacetoxylation; palladium catalyzed; alkenyl tosylsulfonamide; derived alkenyl ... See more keywords