Design and Impact: Navigating the Electrochemical Characterization Methods for Supported Catalysts
Sign Up to like & getrecommendations! Published in 2024 at "ACS Catalysis"
DOI: 10.1021/acscatal.4c03271
Abstract: This review will investigate the impact of electrochemical characterization method design choices on intrinsic catalyst activity measurements by predominantly using the oxygen reduction reaction (ORR) on supported catalysts as a model reaction. The wider use… read more here.
Keywords: supported catalysts; design impact; electrochemical characterization;
Placing gold on a π+-surface: ligand design and impact on reactivity
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc05574k
Abstract: We describe a novel gold chloride complex supported by an ambiphilic phosphine/xanthylium ligand in which the AuCl moiety interacts with the π+ surface of the xanthylium unit as indicated by structural studies. Energy decomposition analyses… read more here.
Keywords: placing gold; surface ligand; design impact; ligand ... See more keywords