Placing gold on a π+-surface: ligand design and impact on reactivity
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DOI: 10.1039/d2sc05574k
Abstract: We describe a novel gold chloride complex supported by an ambiphilic phosphine/xanthylium ligand in which the AuCl moiety interacts with the π+ surface of the xanthylium unit as indicated by structural studies. Energy decomposition analyses… read more here.
Keywords: placing gold; surface ligand; design impact; ligand ... See more keywords