Enantioselective Desymmetrization of Bisphenol Derivatives via Ir-Catalyzed Allylic Dearomatization.
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DOI: 10.1021/jacs.0c09638
Abstract: Spirocyclic hexadienones with multiple stereogenic centers are frequently found in natural products but remain challenging targets to synthesize. Herein, we report the enantioselective desymmetrization of bisphenol derivatives via Ir-catalyzed allylic dearomatization reactions, affording spirocyclic hexadienone… read more here.
Keywords: enantioselective desymmetrization; allylic dearomatization; catalyzed allylic; desymmetrization bisphenol ... See more keywords